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Title: Syntheses, crystal structures and nonlinear optical properties of MS4Pd(dppp) (M = Mo, W)
Authors: Zheng, H.-G.
Tan, W.-L.
Jin, G.-C.
Ji, W. 
Jin, Q.-H.
Huang, X.-Y.
Xin, X.-Q.
Keywords: Crystal structures
Optical properties
Palladium complexes
Thiometallate complexes
Issue Date: 14-Jul-2000
Citation: Zheng, H.-G., Tan, W.-L., Jin, G.-C., Ji, W., Jin, Q.-H., Huang, X.-Y., Xin, X.-Q. (2000-07-14). Syntheses, crystal structures and nonlinear optical properties of MS4Pd(dppp) (M = Mo, W). Inorganica Chimica Acta 305 (1) : 14-18. ScholarBank@NUS Repository.
Abstract: The title compounds [MS4Pd(dppp)] [M = Mo (1), W (2); dppp = Ph2PCH2CH2CH2PPh2] were synthesized for nonlinear optical studies by the reaction of (Et4N)2MS4 (M = Mo, W) and (dppp)PdCl2 in the CH2Cl2-CH3CN. Single-crystal X-ray analyses revealed that the two compounds consisted of a distorted tetrahedral MS4 (M = Mo, W) unit with a Pd atom and two S atom bridges. The Pd atom has a cis-quasisquare coordination geometry with two P donors of dppp and two S donors of MS4. The nonlinear optical properties of 1 and 2 were investigated by a Z-scan technique with 7 ns laser pulses at 532 nm. It was observed that the nonlinear absorption for 1 is very small, but it has considerable large nonlinear refractive index; no nonlinear optical behavior was observed for 2, although it shows a similar structure to that of compound 1. (C) 2000 Elsevier Science S.A.
Source Title: Inorganica Chimica Acta
ISSN: 00201693
DOI: 10.1016/S0020-1693(00)00104-3
Appears in Collections:Staff Publications

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