Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0020-1693(02)01057-5
DC FieldValue
dc.titleSolid-state syntheses of M-Cu-S (M = Mo and W) clusters, crystal structure and non-linear optical properties of {MS4[Cu(p-MeOC6H4)3P] 2}·0.5C6H12
dc.contributor.authorZheng, H.-G.
dc.contributor.authorZhou, J.-L.
dc.contributor.authorTan, W.-L.
dc.contributor.authorNiu, Y.-Y.
dc.contributor.authorJi, W.
dc.contributor.authorXin, X.-Q.
dc.date.accessioned2014-10-16T09:41:23Z
dc.date.available2014-10-16T09:41:23Z
dc.date.issued2002-11-25
dc.identifier.citationZheng, H.-G., Zhou, J.-L., Tan, W.-L., Niu, Y.-Y., Ji, W., Xin, X.-Q. (2002-11-25). Solid-state syntheses of M-Cu-S (M = Mo and W) clusters, crystal structure and non-linear optical properties of {MS4[Cu(p-MeOC6H4)3P] 2}·0.5C6H12. Inorganica Chimica Acta 340 : 29-34. ScholarBank@NUS Repository. https://doi.org/10.1016/S0020-1693(02)01057-5
dc.identifier.issn00201693
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/97962
dc.description.abstractThe title compounds {MS4[Cu(p-MeOC6H4)3P] 2}·0.5C6H12 [M = Mo (1) or W (2)] were synthesized for non-linear optical studies by a solid state reaction of (NH4)2MS4, CuI and (p-MeOC6H4)3P. A single crystal X-ray analysis reveals that 1 possesses a linear skeleton with a Mo center slightly distorted from tetrahedron and two Cu centers distorted from trigonal planar. The non-linear optical properties of 1 were investigated by the Z-scan and picosecond time-resolved pump-probe measurements at 532 nm. The results obtained revealed that thermally induced non-linear effect was dominant in the nanosecond time-scale while stimulated Rayleigh-wing scattering was observed in the picosecond measurement. Its non-linear refractive index was determined to be - 3.52 × 10-17 m2 W-1 for nanosecond time-scale and 4.32 × 10-19 m2 W-1. Nonlinear optical properties of compound 2 were investigated at same condition similar to 1, no non-linear optical behavior was observed for 2, although it might have a similar structure to that of compound 1. © 2002 Elsevier Science B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/S0020-1693(02)01057-5
dc.sourceScopus
dc.subjectCrystal structures
dc.subjectMo(W)-Cu-S cluster
dc.subjectNon-linear absorption
dc.subjectNon-linear refraction
dc.subjectSolid-state reaction
dc.typeArticle
dc.contributor.departmentPHYSICS
dc.description.doi10.1016/S0020-1693(02)01057-5
dc.description.sourcetitleInorganica Chimica Acta
dc.description.volume340
dc.description.page29-34
dc.description.codenICHAA
dc.identifier.isiut000179283000005
Appears in Collections:Staff Publications

Show simple item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

8
checked on Sep 22, 2020

WEB OF SCIENCETM
Citations

7
checked on Sep 15, 2020

Page view(s)

60
checked on Sep 27, 2020

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.