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https://doi.org/10.1006/jmsp.1998.7776
Title: | Analysis of High-Resolution FTIR Spectrum of the ν6Band of H13COOH | Authors: | Ong, P.P. Goh, K.L. Teo, H.H. |
Issue Date: | Apr-1999 | Citation: | Ong, P.P., Goh, K.L., Teo, H.H. (1999-04). Analysis of High-Resolution FTIR Spectrum of the ν6Band of H13COOH. Journal of Molecular Spectroscopy 194 (2) : 203-205. ScholarBank@NUS Repository. https://doi.org/10.1006/jmsp.1998.7776 | Abstract: | The FTIR spectrum of the ν6band of H13COOH has been collected at a resolution of 0.004 cm-1in the frequency range of 1030-1160 cm-1. The ν6band was analyzed to be anA-Bhybrid band and perturbed by the nearby ν8band througha-, andb-Coriolis coupling terms. Using a Watson'sA-reduced Hamiltonian in theIrrepresentation, with the inclusion ofa- andb-Coriolis resonances, a total of 3004 IR transitions of ν6have been analyzed to provide rovibrational constants for thev6= 1 state with a standard deviation of 0.00047 cm-1. The ν6band was found to be centered at 1095.40365 ± 0.00003 cm-1. © 1999 Academic Press. | Source Title: | Journal of Molecular Spectroscopy | URI: | http://scholarbank.nus.edu.sg/handle/10635/95773 | ISSN: | 00222852 | DOI: | 10.1006/jmsp.1998.7776 |
Appears in Collections: | Staff Publications |
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