Please use this identifier to cite or link to this item:
https://doi.org/10.1016/S0022-328X(02)01977-0
| Title: | Cyclic thioether and acyclic thioether-thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III) | Authors: | Goh, L.Y. Teo, M.E. Khoo, S.B. Leong, W.K. Vittal, J.J. |
Issue Date: | 16-Dec-2002 | Citation: | Goh, L.Y., Teo, M.E., Khoo, S.B., Leong, W.K., Vittal, J.J. (2002-12-16). Cyclic thioether and acyclic thioether-thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III). Journal of Organometallic Chemistry 664 (1-2) : 161-169. ScholarBank@NUS Repository. https://doi.org/10.1016/S0022-328X(02)01977-0 | Abstract: | The reaction of [Cp*RuCl2]2 (7) (Cp* = η5-C5Me5) with S(CH2CH2S-)2 (tpdt) and trithiacyclononane (9S3) gave the monomeric complexes Cp*Ru(tpdt) (6) and [Cp*Ru(9S3)](PF6) (8) as dark purple and yellow crystals, respectively. Treatment of 6 with 7 and [(C6Me6)RuCl2]2 (2) led to the isolation of Ru-Ru bonded complexes [Cp*Ru(tpdt)(Ru(Cl)Cp*](PF6) (9) and [Cp Ru(tpd-(tpd)(Ru(C6)](PF6) (10) as dark red and purple crystals, respectively. The complexes, 6 and 8-10 have been spectrally and structurally characterized. | Source Title: | Journal of Organometallic Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/95556 | ISSN: | 0022328X | DOI: | 10.1016/S0022-328X(02)01977-0 |
| Appears in Collections: | Staff Publications |
Show full item record
Files in This Item:
There are no files associated with this item.
SCOPUSTM
Citations
34
checked on Jan 14, 2022
WEB OF SCIENCETM
Citations
29
checked on Jan 14, 2022
Page view(s)
141
checked on Jan 13, 2022
Google ScholarTM
Check
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.