Cyclic thioether and acyclic thioether-thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III)

Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0022-328X(02)01977-0

Title:	Cyclic thioether and acyclic thioether-thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III)
Authors:	Goh, L.Y. Teo, M.E. Khoo, S.B. Leong, W.K. Vittal, J.J.
Issue Date:	16-Dec-2002
Citation:	Goh, L.Y., Teo, M.E., Khoo, S.B., Leong, W.K., Vittal, J.J. (2002-12-16). Cyclic thioether and acyclic thioether-thiolate complexes of pentamethylcyclopentadienyl ruthenium(II, III). Journal of Organometallic Chemistry 664 (1-2) : 161-169. ScholarBank@NUS Repository. https://doi.org/10.1016/S0022-328X(02)01977-0
Abstract:	The reaction of [CpRuCl2]2 (7) (Cp = η5-C5Me5) with S(CH2CH2S-)2 (tpdt) and trithiacyclononane (9S3) gave the monomeric complexes CpRu(tpdt) (6) and [CpRu(9S3)](PF6) (8) as dark purple and yellow crystals, respectively. Treatment of 6 with 7 and [(C6Me6)RuCl2]2 (2) led to the isolation of Ru-Ru bonded complexes [CpRu(tpdt)(Ru(Cl)Cp](PF6) (9) and [Cp Ru(tpd-(tpd)(Ru(C6)](PF6) (10) as dark red and purple crystals, respectively. The complexes, 6 and 8-10 have been spectrally and structurally characterized.
Source Title:	Journal of Organometallic Chemistry
URI:	http://scholarbank.nus.edu.sg/handle/10635/95556
ISSN:	0022328X
DOI:	10.1016/S0022-328X(02)01977-0
Appears in Collections:	Staff Publications

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