Please use this identifier to cite or link to this item: https://doi.org/10.1080/10426500212262
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dc.titleReactions of 1,2,3-triphenyl-1,2,3-triphosphaindan with triruthenium cluster
dc.contributor.authorAng, S.-G.
dc.contributor.authorZhong, X.
dc.contributor.authorAng, H.-G.
dc.date.accessioned2014-10-16T08:48:29Z
dc.date.available2014-10-16T08:48:29Z
dc.date.issued2002
dc.identifier.citationAng, S.-G., Zhong, X., Ang, H.-G. (2002). Reactions of 1,2,3-triphenyl-1,2,3-triphosphaindan with triruthenium cluster. Phosphorus, Sulfur and Silicon and Related Elements 177 (6-7) : 1463-1467. ScholarBank@NUS Repository. https://doi.org/10.1080/10426500212262
dc.identifier.issn10426507
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95492
dc.description.abstractReactions of 1,2,3-triphenyl-1,2,3-triphosphaindan (I), C6H4(PPh)3, with [Ru3(CO)12] under various conditions result in the rupture of the P3C2-ring framework in the ligand and the cleavage of the M-M bonds in the parent cluster, leading to the formation of a series of phosphido bridged and phosphinidene capped trinuclear or polyhedral ruthenium clusters: a tetra-nuclear butterfly-like cluster [Ru4(CO)10(μ3-PPh)] 1, a tri-nuclear bent-chain skeleton cluster [Ru3(CO)9 {μ3-η3-PPhC6H4(PPh) 2}] 2, and a nonplanar six-atom-raft rhombic geometry cluster [Ru6(CO)12(μ3-PPh)(μ4-PPh) 2(μ3-η2-C6H4)] 3. All compounds have been fully characterized by spectroscopic methods, while the molecular structures of the new compounds 2 and 3 are established by X-ray crystallographic techniques.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1080/10426500212262
dc.sourceScopus
dc.subjectCluster
dc.subjectPhosphorus
dc.subjectRuthenium
dc.subjectTriphosphaindan
dc.typeConference Paper
dc.contributor.departmentCHEMISTRY
dc.contributor.departmentMATERIALS SCIENCE
dc.description.doi10.1080/10426500212262
dc.description.sourcetitlePhosphorus, Sulfur and Silicon and Related Elements
dc.description.volume177
dc.description.issue6-7
dc.description.page1463-1467
dc.identifier.isiut000176800600020
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