Please use this identifier to cite or link to this item: https://doi.org/10.1021/om010246s
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dc.titleα,ω-bis(trichlorostannyl)alkanes as bis(monodentate) Lewis acids toward halide ions
dc.contributor.authorZobel, B.
dc.contributor.authorDuthie, A.
dc.contributor.authorDakternieks, D.
dc.contributor.authorTiekink, E.R.T.
dc.date.accessioned2014-10-16T08:47:43Z
dc.date.available2014-10-16T08:47:43Z
dc.date.issued2001-07-23
dc.identifier.citationZobel, B., Duthie, A., Dakternieks, D., Tiekink, E.R.T. (2001-07-23). α,ω-bis(trichlorostannyl)alkanes as bis(monodentate) Lewis acids toward halide ions. Organometallics 20 (15) : 3347-3350. ScholarBank@NUS Repository. https://doi.org/10.1021/om010246s
dc.identifier.issn02767333
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95427
dc.description.abstractThe reactions between X3Sn(CH2)nSnX3 (X = Cl, Br; n = 1, 3, 4, 8) and halide in solution are described. 119Sn NMR spectroscopy (CD2Cl2) indicates formation of five-coordinate dinuclear 1:2 adducts, [X4Sn(CH2)nSnX4]2-, with chloride and bromide. A trigonal-bipyramidal geometry has been confirmed in the solid state for the compound having X = Cl and n = 4. In contrast, fluoride reacts with X3Sn(CH2)nSnX3 to give six-coordinate tin species, [F5Sn(CH2)nSnF5].4- There was no evidence indicating that the tin atoms could act as a bidentate acid.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1021/om010246s
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1021/om010246s
dc.description.sourcetitleOrganometallics
dc.description.volume20
dc.description.issue15
dc.description.page3347-3350
dc.description.codenORGND
dc.identifier.isiut000169981000021
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