Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.cplett.2005.07.110
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dc.titleVibrational studies of the reactions of acetophenone with Si(1 0 0)-2 × 1
dc.contributor.authorHuang, H.G.
dc.contributor.authorHuang, J.Y.
dc.contributor.authorCai, Y.H.
dc.contributor.authorXu, G.Q.
dc.date.accessioned2014-10-16T08:47:29Z
dc.date.available2014-10-16T08:47:29Z
dc.date.issued2005-10-03
dc.identifier.citationHuang, H.G., Huang, J.Y., Cai, Y.H., Xu, G.Q. (2005-10-03). Vibrational studies of the reactions of acetophenone with Si(1 0 0)-2 × 1. Chemical Physics Letters 414 (1-3) : 143-147. ScholarBank@NUS Repository. https://doi.org/10.1016/j.cplett.2005.07.110
dc.identifier.issn00092614
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95405
dc.description.abstractThe covalent attachment of acetophenone on Si(1 0 0) has been investigated using high-resolution electron energy loss spectroscopy (HREELS) and density functional theory (DFT) calculations. The HREELS spectrum of the chemisorbed monolayer shows the absence of the CO stretching mode around 1687 cm -1 coupled with the retention of all vibrational signatures of a phenyl ring. The experimental results unambiguously demonstrate a [2 + 2]-like cycloaddition mechanism for acetophenone chemisorption on Si(1 0 0) through the binding between the CO group and a Si dimer, consistent with the prediction of DFT calculations. © 2005 Elsevier B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.cplett.2005.07.110
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/j.cplett.2005.07.110
dc.description.sourcetitleChemical Physics Letters
dc.description.volume414
dc.description.issue1-3
dc.description.page143-147
dc.description.codenCHPLB
dc.identifier.isiut000232460400028
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