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Title: Triosmium carbonyl cluster derivatives containing pentameric phenyl cyclopolyphosphine
Authors: Ang, H.-G. 
Ang, S.-G. 
Kwik, W.-L. 
Zhang, Q.
Keywords: Cluster
Crystal structure
Issue Date: 11-Jan-1995
Citation: Ang, H.-G.,Ang, S.-G.,Kwik, W.-L.,Zhang, Q. (1995-01-11). Triosmium carbonyl cluster derivatives containing pentameric phenyl cyclopolyphosphine. Journal of Organometallic Chemistry 485 (1-2) : C10-C13. ScholarBank@NUS Repository.
Abstract: The reactions of the pentaphenylcyclopentaphosphine with [Os3(CO)10(NCCH3)2] afforded a pair of inversion isomers, (1) and (2). [Os3(CO)11(C6H5P)5] (3) and [{Os3(CO)11}2(C6H5P)5] (4) were obtained by the treatment of the same ligand with [Os3(CO)11(NCCH3)]. The four new triosmium clusters have been shown by X-ray crystallography to contain an intact cyclopolyphosphine ring in each case. © 1995.
Source Title: Journal of Organometallic Chemistry
ISSN: 0022328X
Appears in Collections:Staff Publications

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