Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/95341
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dc.titleTransition metal complexes of 1,3-bis(thiomorpholino)propane: Crystal structure and dynamic 1H NMR study
dc.contributor.authorLi, Y.
dc.contributor.authorLai, Y.-H.
dc.contributor.authorMok, K.F.
dc.contributor.authorDrew, M.G.B.
dc.date.accessioned2014-10-16T08:46:41Z
dc.date.available2014-10-16T08:46:41Z
dc.date.issued1999-02-02
dc.identifier.citationLi, Y.,Lai, Y.-H.,Mok, K.F.,Drew, M.G.B. (1999-02-02). Transition metal complexes of 1,3-bis(thiomorpholino)propane: Crystal structure and dynamic 1H NMR study. Inorganica Chimica Acta 285 (1) : 31-38. ScholarBank@NUS Repository.
dc.identifier.issn00201693
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95341
dc.description.abstractComplexes of 1,3-bis(thiomorpholino)propane (L) with Zn(II), Pd(II), Pt(II) and Rh(III) of the formula [ZnLCl2], [ML](ClO4)2, (M = Pd and Pt), [RhLCl2]Cl·4H2O and [RhLCl2]PF6 were prepared and characterised. The molecular structures of [ZnLCl2], [PdL](ClO4)2 and [RhLCl2]PF6 were determined by X-ray diffraction. In [ZnLCl2], the ligand acts in a bidentate fashion using its two N atoms while the two S atoms remain free and the coordination structure is a distorted tetrahedron. [PdL](ClO4)2 possesses a distorted square planar coordination geometry with all the four hetero atoms being coordinated. The coordination structure of [RhLCl2]PF6 is a distorted octahedron with the two Cl atoms in trans position and L also acting as a tetradentate ligand. In addition to the crystal structures, the dynamic 1H NMR behaviour of the three complexes were also investigated.
dc.sourceScopus
dc.subjectCrystal structures
dc.subjectThiomorpholine complexes
dc.subjectTransition metal complexes
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.sourcetitleInorganica Chimica Acta
dc.description.volume285
dc.description.issue1
dc.description.page31-38
dc.description.codenICHAA
dc.identifier.isiutNOT_IN_WOS
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