Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2008.01.025
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dc.titleThe reaction of triosmium and -ruthenium clusters with bifunctional ligands
dc.contributor.authorLi, C.
dc.contributor.authorLeong, W.K.
dc.date.accessioned2014-10-16T08:45:43Z
dc.date.available2014-10-16T08:45:43Z
dc.date.issued2008-04-01
dc.identifier.citationLi, C., Leong, W.K. (2008-04-01). The reaction of triosmium and -ruthenium clusters with bifunctional ligands. Journal of Organometallic Chemistry 693 (7) : 1292-1300. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2008.01.025
dc.identifier.issn0022328X
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95259
dc.description.abstractThe reaction of [Os3(CO)10(μ-H)(μ-OH)], 1, or [Os3(CO)10(NCCH3)2], 2, with bifunctional ligands carrying -OH, -SH and -COOH groups affords, as the major product, clusters of the general formula [Os3(CO)10(μ-H)(μ-E{frown}E′H)] (E, E′ = O, S or COO). In some cases, a minor product with general formula [Os3(CO)10(μ-H)(μ,μ-E{frown}E′)Os3(CO)10(μ-H)] was also obtained. With Ru3(CO)12, 3b, only the first type of products is obtained. The structures of eight of the compounds have also been determined by single crystal X-ray crystallography. © 2008 Elsevier B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jorganchem.2008.01.025
dc.sourceScopus
dc.subjectBifunctional ligand
dc.subjectCluster
dc.subjectOsmium
dc.subjectRuthenium
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/j.jorganchem.2008.01.025
dc.description.sourcetitleJournal of Organometallic Chemistry
dc.description.volume693
dc.description.issue7
dc.description.page1292-1300
dc.description.codenJORCA
dc.identifier.isiut000254409700018
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