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Title: The reaction of triosmium and -ruthenium clusters with bifunctional ligands
Authors: Li, C.
Leong, W.K. 
Keywords: Bifunctional ligand
Issue Date: 1-Apr-2008
Citation: Li, C., Leong, W.K. (2008-04-01). The reaction of triosmium and -ruthenium clusters with bifunctional ligands. Journal of Organometallic Chemistry 693 (7) : 1292-1300. ScholarBank@NUS Repository.
Abstract: The reaction of [Os3(CO)10(μ-H)(μ-OH)], 1, or [Os3(CO)10(NCCH3)2], 2, with bifunctional ligands carrying -OH, -SH and -COOH groups affords, as the major product, clusters of the general formula [Os3(CO)10(μ-H)(μ-E{frown}E′H)] (E, E′ = O, S or COO). In some cases, a minor product with general formula [Os3(CO)10(μ-H)(μ,μ-E{frown}E′)Os3(CO)10(μ-H)] was also obtained. With Ru3(CO)12, 3b, only the first type of products is obtained. The structures of eight of the compounds have also been determined by single crystal X-ray crystallography. © 2008 Elsevier B.V. All rights reserved.
Source Title: Journal of Organometallic Chemistry
ISSN: 0022328X
DOI: 10.1016/j.jorganchem.2008.01.025
Appears in Collections:Staff Publications

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