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https://doi.org/10.1016/j.jorganchem.2008.01.025
Title: | The reaction of triosmium and -ruthenium clusters with bifunctional ligands | Authors: | Li, C. Leong, W.K. |
Keywords: | Bifunctional ligand Cluster Osmium Ruthenium |
Issue Date: | 1-Apr-2008 | Citation: | Li, C., Leong, W.K. (2008-04-01). The reaction of triosmium and -ruthenium clusters with bifunctional ligands. Journal of Organometallic Chemistry 693 (7) : 1292-1300. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2008.01.025 | Abstract: | The reaction of [Os3(CO)10(μ-H)(μ-OH)], 1, or [Os3(CO)10(NCCH3)2], 2, with bifunctional ligands carrying -OH, -SH and -COOH groups affords, as the major product, clusters of the general formula [Os3(CO)10(μ-H)(μ-E{frown}E′H)] (E, E′ = O, S or COO). In some cases, a minor product with general formula [Os3(CO)10(μ-H)(μ,μ-E{frown}E′)Os3(CO)10(μ-H)] was also obtained. With Ru3(CO)12, 3b, only the first type of products is obtained. The structures of eight of the compounds have also been determined by single crystal X-ray crystallography. © 2008 Elsevier B.V. All rights reserved. | Source Title: | Journal of Organometallic Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/95259 | ISSN: | 0022328X | DOI: | 10.1016/j.jorganchem.2008.01.025 |
Appears in Collections: | Staff Publications |
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