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Title: Synthesis, structure and dehydrogenation of magnesium amidoborane monoammoniate
Authors: Chua, Y.S.
Wu, G.
Xiong, Z.
Karkamkar, A.
Guo, J.
Jian, M.
Wong, M.W. 
Autrey, T.
Chen, P.
Issue Date: 21-Aug-2010
Citation: Chua, Y.S., Wu, G., Xiong, Z., Karkamkar, A., Guo, J., Jian, M., Wong, M.W., Autrey, T., Chen, P. (2010-08-21). Synthesis, structure and dehydrogenation of magnesium amidoborane monoammoniate. Chemical Communications 46 (31) : 5752-5754. ScholarBank@NUS Repository.
Abstract: Magnesium amidoborane monoammoniate (Mg(NH2BH3) 2·NH3) which crystallizes in a monoclinic structure (space group P21/a) has been synthesized by reacting MgNH with NH3BH3. Dihydrogen bonds are established between coordinated NH3 and BH3 of [NH2BH 3]- in the structure, promoting stoichiometric conversion of NH3 to H2. © 2010 The Royal Society of Chemistry.
Source Title: Chemical Communications
ISSN: 13597345
DOI: 10.1039/c0cc01260b
Appears in Collections:Staff Publications

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