Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0022-328X(02)02120-4
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dc.titleSynthesis, NMR and structural studies of cluster derivatives derived from reactions of 1,2,3-triphenyl-1,2,3-triphosphaindan with [Os3(CO)10(μ-H)2]
dc.contributor.authorAng, S.-G.
dc.contributor.authorZhong, X.
dc.contributor.authorAng, H.-G.
dc.date.accessioned2014-10-16T08:44:33Z
dc.date.available2014-10-16T08:44:33Z
dc.date.issued2003-01-03
dc.identifier.citationAng, S.-G., Zhong, X., Ang, H.-G. (2003-01-03). Synthesis, NMR and structural studies of cluster derivatives derived from reactions of 1,2,3-triphenyl-1,2,3-triphosphaindan with [Os3(CO)10(μ-H)2]. Journal of Organometallic Chemistry 665 (1-2) : 218-225. ScholarBank@NUS Repository. https://doi.org/10.1016/S0022-328X(02)02120-4
dc.identifier.issn0022328X
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95162
dc.description.abstractReactions of 1,2,3-triphenyl-1,2,3-triphosphaindan (I) with [Os3(CO)10(μ-H)2] at various conditions afford a series of osmium carbonyl cluster derivatives: an open bent-chain trinuclear cluster [Os3(CO)9{μ3- η3-PPhC6H4(PPh)2}] (1), a di-substituted bridged trinuclear cluster [Os3(CO)10 {μ-1,3-η2-C6H4(PPh)3}] (2), a 1,3-linked bis-trinuclear hydride cluster {μ3-η3-{(PPh)2C6H 4PPh}] (4), and a closed trinuclear cluster [(μ-H)Os3 (CO)8{C6H4(PPh)3}{μ-η 3-{C6H4(PPh)2PC6 H4}] (5). All the compounds obtained have been fully characterized by spectroscopic methods (IR, FABMS, 1H- and 31P-NMR spectroscopy), and the molecular structures of 3, 4, 5 are established by X-ray crystallography. © 2002 Elsevier Science B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/S0022-328X(02)02120-4
dc.sourceScopus
dc.subject31P-NMR
dc.subjectCrystal structures
dc.subjectOsmium cluster
dc.subjectTriphosphaindan
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.contributor.departmentMATERIALS SCIENCE
dc.description.doi10.1016/S0022-328X(02)02120-4
dc.description.sourcetitleJournal of Organometallic Chemistry
dc.description.volume665
dc.description.issue1-2
dc.description.page218-225
dc.description.codenJORCA
dc.identifier.isiut000180689100029
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