Please use this identifier to cite or link to this item:
|Title:||Synthesis of functionalized tetracene dicarboxylic imides||Authors:||Yin, J.
|Issue Date:||1-Dec-2010||Citation:||Yin, J., Zhang, K., Jiao, C., Li, J., Chi, C., Wu, J. (2010-12-01). Synthesis of functionalized tetracene dicarboxylic imides. Tetrahedron Letters 51 (48) : 6313-6315. ScholarBank@NUS Repository. https://doi.org/10.1016/j.tetlet.2010.09.116||Abstract:||For the first time, a synthesis of tetracene dicarboxylic imides was established with 1,2,3,4-tetrahydrotetracene (1) instead of tetracene as the starting material. Mono-bromination of 1 by CuBr2 followed by a Friedel-Crafts reaction, oxidation, and imidization gave the tetrahydrotetracene carboxylic imides 5a-b. Subsequent oxidative dehydrogenation of 5a-b with DDQ afforded the functional tetracene dicarboxylic imide monobromides 6a-b, which can be further functionalized to provide functional materials such as the 'donor-acceptor' type compounds 7a-b. © 2010 Elsevier Ltd. All rights reserved.||Source Title:||Tetrahedron Letters||URI:||http://scholarbank.nus.edu.sg/handle/10635/95124||ISSN:||00404039||DOI:||10.1016/j.tetlet.2010.09.116|
|Appears in Collections:||Staff Publications|
Show full item record
Files in This Item:
There are no files associated with this item.
checked on Feb 14, 2020
WEB OF SCIENCETM
checked on Feb 6, 2020
checked on Feb 16, 2020
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.