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https://doi.org/10.1016/S0020-1693(03)00133-6
Title: | Synthesis of diimineplatinum(II) complexes containing the 1,2-dicarba-closo-dodecaborane(12)-1-thiolato ligand | Authors: | Todd, J.A. Caiazza, D. Tiekink, E.R.T. Rendina, L.M. |
Keywords: | Carborane Crystal structures Platinum complexes Thiolato ligand |
Issue Date: | 6-Aug-2003 | Citation: | Todd, J.A., Caiazza, D., Tiekink, E.R.T., Rendina, L.M. (2003-08-06). Synthesis of diimineplatinum(II) complexes containing the 1,2-dicarba-closo-dodecaborane(12)-1-thiolato ligand. Inorganica Chimica Acta 352 : 208-212. ScholarBank@NUS Repository. https://doi.org/10.1016/S0020-1693(03)00133-6 | Abstract: | The novel air- and moisture-stable platinum(II)-diimine complexes containing the 1,2-dicarba-closo-dodecaborane(12)-1-thiolato ligand, [PtCl(1-S-C2B10H11)(N-N)] and [Pt(1-S-C2B10H11)2(N-N)] (N-N=2,2′-bipyridine (bipy), 1,10-phenanthroline (phen)), were prepared by a facile two-step synthesis from the corresponding dichloroplatinum(II) precursors. All complexes were characterized primarily by multinuclear (1H, 11B, 13C, and 195Pt) 1D and 2D NMR spectroscopy. The structure of [Pt(1-S-C2B10H11)2(bipy)] was confirmed by single-crystal X-ray crystallography. © 2003 Elsevier Science B.V. All rights reserved. | Source Title: | Inorganica Chimica Acta | URI: | http://scholarbank.nus.edu.sg/handle/10635/95118 | ISSN: | 00201693 | DOI: | 10.1016/S0020-1693(03)00133-6 |
Appears in Collections: | Staff Publications |
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