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Title: Synthesis of diimineplatinum(II) complexes containing the 1,2-dicarba-closo-dodecaborane(12)-1-thiolato ligand
Authors: Todd, J.A.
Caiazza, D.
Tiekink, E.R.T. 
Rendina, L.M.
Keywords: Carborane
Crystal structures
Platinum complexes
Thiolato ligand
Issue Date: 6-Aug-2003
Citation: Todd, J.A., Caiazza, D., Tiekink, E.R.T., Rendina, L.M. (2003-08-06). Synthesis of diimineplatinum(II) complexes containing the 1,2-dicarba-closo-dodecaborane(12)-1-thiolato ligand. Inorganica Chimica Acta 352 : 208-212. ScholarBank@NUS Repository.
Abstract: The novel air- and moisture-stable platinum(II)-diimine complexes containing the 1,2-dicarba-closo-dodecaborane(12)-1-thiolato ligand, [PtCl(1-S-C2B10H11)(N-N)] and [Pt(1-S-C2B10H11)2(N-N)] (N-N=2,2′-bipyridine (bipy), 1,10-phenanthroline (phen)), were prepared by a facile two-step synthesis from the corresponding dichloroplatinum(II) precursors. All complexes were characterized primarily by multinuclear (1H, 11B, 13C, and 195Pt) 1D and 2D NMR spectroscopy. The structure of [Pt(1-S-C2B10H11)2(bipy)] was confirmed by single-crystal X-ray crystallography. © 2003 Elsevier Science B.V. All rights reserved.
Source Title: Inorganica Chimica Acta
ISSN: 00201693
DOI: 10.1016/S0020-1693(03)00133-6
Appears in Collections:Staff Publications

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