Please use this identifier to cite or link to this item: https://doi.org/10.1002/chem.200900133
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dc.titleSynthesis of aryl sulfides by decarboxylative C-S cross-couplings
dc.contributor.authorDuan, Z.
dc.contributor.authorRanjit, S.
dc.contributor.authorZhang, P.
dc.contributor.authorLiu, X.
dc.date.accessioned2014-10-16T08:43:58Z
dc.date.available2014-10-16T08:43:58Z
dc.date.issued2009-04-06
dc.identifier.citationDuan, Z., Ranjit, S., Zhang, P., Liu, X. (2009-04-06). Synthesis of aryl sulfides by decarboxylative C-S cross-couplings. Chemistry - A European Journal 15 (15) : 3666-3669. ScholarBank@NUS Repository. https://doi.org/10.1002/chem.200900133
dc.identifier.issn09476539
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95115
dc.description.abstractA study was conducted to demonstrate the transition-metal-catalyzed synthesis of aryl sulfides by decarboxylative C-S cross-couplings. Coupling reaction of 2-nitrobenzoic acid with 1-octanethiol were carried in the presence of different combinations of transition-metal catalysts at elevated temperatures to investigate the synthesis process and identify an effective catalyst system. The investigations showed that these reactions formed decarboxylative coupling products containing a mixture of nitrobenzene and aminobenzene sulfides. It was also demonstrated that reactions conducted with monometallic PdII, CuII, or bimetallic CuII, AgI, PdII, and AgI catalysts resulted in low conversions of starting materials. A wide range of aryl carboxylic acids were tested as substrates for C-S coupling to expand the scope of the method.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1002/chem.200900133
dc.sourceScopus
dc.subjectCarboxylic acid
dc.subjectCross-coupling
dc.subjectDecarboxylation reaction
dc.subjectThiols
dc.subjectTransition metals
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1002/chem.200900133
dc.description.sourcetitleChemistry - A European Journal
dc.description.volume15
dc.description.issue15
dc.description.page3666-3669
dc.description.codenCEUJE
dc.identifier.isiut000265162900005
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