Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/95110
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dc.titleSynthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os3(μ-H)(CO)10(μ-P(C6F5)H)]: cleavage of a PC bond of a secondary phosphine
dc.contributor.authorAng, H.G.
dc.contributor.authorKwik, W.L.
dc.contributor.authorLeong, W.K.
dc.contributor.authorJohnson, B.F.G.
dc.contributor.authorLewis, J.
dc.contributor.authorRaithby, P.R.
dc.date.accessioned2014-10-16T08:43:55Z
dc.date.available2014-10-16T08:43:55Z
dc.date.issued1990-10-16
dc.identifier.citationAng, H.G.,Kwik, W.L.,Leong, W.K.,Johnson, B.F.G.,Lewis, J.,Raithby, P.R. (1990-10-16). Synthesis and X-ray structural characterisation of the phosphido-bridged triosmium carbonyl cluster [Os3(μ-H)(CO)10(μ-P(C6F5)H)]: cleavage of a PC bond of a secondary phosphine. Journal of Organometallic Chemistry 396 (2-3) : C43-C46. ScholarBank@NUS Repository.
dc.identifier.issn0022328X
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95110
dc.description.abstractThe reaction of the anion [Os3H(CO)11]- with bis(pentafluorophenyl)phosphine, (C6F5)2PH, results in the cleavage of a PC bond and the formation of the bridged phosphido cluster [Os3(μ-H)(CO)10(μ-P(C6F6)H)]. The structure of this product has been confirmed by a single-crystal X-ray diffraction study which shows that the P(C6F5)H ligand and the hydrido bridge the long edge (2.916(1) Å) of the isosceles osmium triangle. © 1990.
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.sourcetitleJournal of Organometallic Chemistry
dc.description.volume396
dc.description.issue2-3
dc.description.pageC43-C46
dc.description.codenJORCA
dc.identifier.isiutNOT_IN_WOS
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