Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2005.11.061
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dc.titleSynthesis and structure of some ruthenium-rhenium heterodinuclear complexes and their catalytic activity in the addition of carboxylic acids to phenylacetylene
dc.contributor.authorYe, S.
dc.contributor.authorLeong, W.K.
dc.date.accessioned2014-10-16T08:43:49Z
dc.date.available2014-10-16T08:43:49Z
dc.date.issued2006-03-01
dc.identifier.citationYe, S., Leong, W.K. (2006-03-01). Synthesis and structure of some ruthenium-rhenium heterodinuclear complexes and their catalytic activity in the addition of carboxylic acids to phenylacetylene. Journal of Organometallic Chemistry 691 (6) : 1216-1222. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2005.11.061
dc.identifier.issn0022328X
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95101
dc.description.abstractThe salt elimination reaction of Na[Re(CO)5] with Cp*Ru(dppm)Cl, CpRu(dppm)Cl or CpRu(CO)2Cl afforded the heterodinuclear species Cp*Ru(μ-CO)2(μ-dppm)Re(CO) 3, Cp(CO)Ru(μ-dppm)Re(CO)4, or Cp(CO) 2RuRe(CO)5, respectively, in moderate yields. An orthometallated species, Cp*(CO)Ru(μ-H)[μ-PhP(C6H 4)CH2PPh2]Re(CO)3, was also obtained from the first reaction. All these heterodinuclear products have been characterised crystallographically. They also showed good catalytic activity for the addition of carboxylic acids to phenylacetylene to afford the anti-Markovnikov products selectively. © 2005 Elsevier B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jorganchem.2005.11.061
dc.sourceScopus
dc.subjectAddition of carboxylic acid
dc.subjectAlkyne
dc.subjectAnti-Markovnikov addition
dc.subjectCatalysis
dc.subjectHeterodinuclear
dc.subjectRhenium
dc.subjectRuthenium
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/j.jorganchem.2005.11.061
dc.description.sourcetitleJournal of Organometallic Chemistry
dc.description.volume691
dc.description.issue6
dc.description.page1216-1222
dc.description.codenJORCA
dc.identifier.isiut000235856000018
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