Please use this identifier to cite or link to this item: https://doi.org/10.1021/om050781i
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dc.titleSynthesis and structural characterization of the first bis(benzimidazolin- 2-ylidene) complexes of nickel(II)
dc.contributor.authorHuynh, H.V.
dc.contributor.authorHoltgrewe, C.
dc.contributor.authorPape, T.
dc.contributor.authorKoh, L.L.
dc.contributor.authorHahn, E.
dc.date.accessioned2014-10-16T08:43:41Z
dc.date.available2014-10-16T08:43:41Z
dc.date.issued2006-01-02
dc.identifier.citationHuynh, H.V., Holtgrewe, C., Pape, T., Koh, L.L., Hahn, E. (2006-01-02). Synthesis and structural characterization of the first bis(benzimidazolin- 2-ylidene) complexes of nickel(II). Organometallics 25 (1) : 245-249. ScholarBank@NUS Repository. https://doi.org/10.1021/om050781i
dc.identifier.issn02767333
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95090
dc.description.abstractThe reaction of Ni(OAc)2 with the benzimidazolium salts 1,3-dimethylbenzimidazolium iodide (1), 1,3-bis(2-propenyl)benzimidazolium bromide (2), 1,3-dipropylbenzimidazolium bromide (3), 1-(2-propenyl)-3- methylbenzimidazolium bromide (6), and 1-propyl-3-methylbenzimidazolium iodide (7) in molten [Bu4N]X (X = Br, I, BF4) as ionic liquid afforded novel square-planar nickel(II) bis(benzimidazolin-2-ylidene) complexes of the general formula trans-[NiX2(NHC)2] (X = I, NHC = 1,3-dimethylbenzimidazolin-2-ylidene, 8; X = Br, NHC = 1,3-bis(2-propenyl) benzimidazolin-2-ylidene, 9; X = Br, NHC = 1,3-dipropylbenzimidazolin-2-ylidene, 10; X = Br, NHC = 1-(2-propenyl)-3-methylbenzimidazolin-2-ylidene, 11; X = I, NHC = 1-propyl-3-methylbenzimidazolin-2-ylidene, 12). X-ray diffraction studies of 8-12 reveal a square-planar coordination geometry for all complexes with the carbene ligands arranged in a trans fashion. © 2006 American Chemical Society.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1021/om050781i
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1021/om050781i
dc.description.sourcetitleOrganometallics
dc.description.volume25
dc.description.issue1
dc.description.page245-249
dc.description.codenORGND
dc.identifier.isiut000234301500036
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