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|Title:||Synthesis and properties of N-Bis(trifluoromethyl) nitroxy-iminoarsine (CF3)2NONAsH: The first two-coordinate iminoarsine containing AN AsN double bond||Authors:||Ang, H.G.
|Issue Date:||1989||Citation:||Ang, H.G.,Lee, F.K. (1989). Synthesis and properties of N-Bis(trifluoromethyl) nitroxy-iminoarsine (CF3)2NONAsH: The first two-coordinate iminoarsine containing AN AsN double bond. Polyhedron 8 (11) : 1461-1462. ScholarBank@NUS Repository.||Abstract:||(CF3)2NONAsH (A), the first example of a two-coordinate iminoarsine, was synthesized by a condensation reaction between (CF3)2NONO and AsH3. It underwent substitution reactions with the (CF3)2NO radical to afford (CF3)2NONAsON(CF3)2. Both the iminoarsines, (CF3)2NONAsR (where R = H and ON(CF3)2), underwent addition reactions with HI to give (CF3)2NONHAsRI. © 1989.||Source Title:||Polyhedron||URI:||http://scholarbank.nus.edu.sg/handle/10635/95079||ISSN:||02775387|
|Appears in Collections:||Staff Publications|
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