Please use this identifier to cite or link to this item: https://doi.org/10.1021/om700706r
DC FieldValue
dc.titleSynthesis and electronic spectroscopy of luminescent cyclometalated platinum-anthracenyl complexes
dc.contributor.authorHu, J.
dc.contributor.authorLin, R.
dc.contributor.authorYip, J.H.K.
dc.contributor.authorWong, K.-Y.
dc.contributor.authorDik-Lung, M.
dc.contributor.authorVittal, J.J.
dc.date.accessioned2014-10-16T08:43:24Z
dc.date.available2014-10-16T08:43:24Z
dc.date.issued2007-12-17
dc.identifier.citationHu, J., Lin, R., Yip, J.H.K., Wong, K.-Y., Dik-Lung, M., Vittal, J.J. (2007-12-17). Synthesis and electronic spectroscopy of luminescent cyclometalated platinum-anthracenyl complexes. Organometallics 26 (26) : 6533-6543. ScholarBank@NUS Repository. https://doi.org/10.1021/om700706r
dc.identifier.issn02767333
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95064
dc.description.abstractDicyclometalated complexes syn- and anti-[Pt2(L) 2(PAnP-H2)](OTf)2 (Pt2) are synthesized from reactions of 9,10-bis(diphenylphosphino)anthracene (PAnP) and Pt(L)(OTf)2 (L = diphosphines, OTf = CF3SO3). Because of metal perturbation on the electronic structure of the anthracenyl ring, the 1B2u - ← 1Ag transition, which is forbidden in anthracene, is observed in the electronic spectra of Pt2. The complexes display fluorescence arising from the ligand-centered Si excited state. No significant heavy atom effect is observed in the Pt2 complexes. To understand the effect of the number of Pt ions on the extent of perturbation, a mononuclear analogue, [Pt(dppe)(PAn-H)] ClO4 (PAn = 9-diphenylphosphinoanthracene), is prepared and its spectroscopy studied. © 2007 American Chemical Society.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1021/om700706r
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1021/om700706r
dc.description.sourcetitleOrganometallics
dc.description.volume26
dc.description.issue26
dc.description.page6533-6543
dc.description.codenORGND
dc.identifier.isiut000251547000009
Appears in Collections:Staff Publications

Show simple item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

46
checked on May 10, 2022

WEB OF SCIENCETM
Citations

41
checked on May 10, 2022

Page view(s)

181
checked on May 12, 2022

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.