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https://scholarbank.nus.edu.sg/handle/10635/95053
DC Field | Value | |
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dc.title | Synthesis and crystal structure of an indenylnickel(II) NHC complex (Ind)NiBr(1,3-bisbenzylimidazol-2-ylidene) | |
dc.contributor.author | Hu, D.-M. | |
dc.contributor.author | Sun, H.-M. | |
dc.contributor.author | Wang, Y.-S. | |
dc.contributor.author | Shen, Q. | |
dc.contributor.author | Xue, F. | |
dc.date.accessioned | 2014-10-16T08:43:16Z | |
dc.date.available | 2014-10-16T08:43:16Z | |
dc.date.issued | 2006 | |
dc.identifier.citation | Hu, D.-M.,Sun, H.-M.,Wang, Y.-S.,Shen, Q.,Xue, F. (2006). Synthesis and crystal structure of an indenylnickel(II) NHC complex (Ind)NiBr(1,3-bisbenzylimidazol-2-ylidene). Jiegou Huaxue 25 (10) : 1255-1259. ScholarBank@NUS Repository. | |
dc.identifier.issn | 02545861 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/95053 | |
dc.description.abstract | The complex (Ind)NiBr(1,3-bisbenzylimidazol-2-ylidene) (Ind = indenyl) 1 has been prepared in ca. 65% yield via the reaction of (Ind)2Ni with an equivalent of 1,3-bis-benzylimidazolium bromide in THF/CH2Cl 2 at 45°C, supported by elemental analysis, NMR spectroscopy and X-ray crystal determination. The crystal belongs to the triclinic system, space group P1 with a = 7.072(1), b = 11.264(2), c = 14.541(3) Å, α = 102.21(3), β = 93.44(3), γ = 90.81(3)°, V = 1129.7(4) Å3, Z = 2, Mr = 502.08, Dc = 1.476 g/cm3, F(000) = 512, μ = 2.642 mm-1, R = 0.0490 and wR = 0.1137 for 3913 observed reflections (I > 2σ(I)). The center nickel atom is coordinated by a bromide ligand, a carbene carbon and three carbon atoms of the five-membered indenyl group to form either a highly distorted square pyramid or a highly distorted square plane. | |
dc.source | Scopus | |
dc.subject | Indenyl ligand | |
dc.subject | N-heterocyclic carbene | |
dc.subject | Nickel complex | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.sourcetitle | Jiegou Huaxue | |
dc.description.volume | 25 | |
dc.description.issue | 10 | |
dc.description.page | 1255-1259 | |
dc.identifier.isiut | NOT_IN_WOS | |
Appears in Collections: | Staff Publications |
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