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Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.ica.2010.03.068
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dc.titleSynthesis and characterisation of adducts of [Pt2(μ-S) 2(PPh3)4] with organo-palladium and platinum-hydride substrates
dc.contributor.authorWhite, B.C.
dc.contributor.authorHarrison, D.
dc.contributor.authorHenderson, W.
dc.contributor.authorNicholson, B.K.
dc.contributor.authorAndy Hor, T.S.
dc.date.accessioned2014-10-16T08:42:58Z
dc.date.available2014-10-16T08:42:58Z
dc.date.issued2010-08-10
dc.identifier.citationWhite, B.C., Harrison, D., Henderson, W., Nicholson, B.K., Andy Hor, T.S. (2010-08-10). Synthesis and characterisation of adducts of [Pt2(μ-S) 2(PPh3)4] with organo-palladium and platinum-hydride substrates. Inorganica Chimica Acta 363 (11) : 2387-2393. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ica.2010.03.068
dc.identifier.issn00201693
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/95027
dc.description.abstractThe reactions of [Pt2(μ-S)2(PPh3) 4] towards a range of palladium(II) complexes containing organometallic ligands (cyclopalladated N-donor ligands, η3- allyl, phenyl) have been explored, leading to the formation of a series of cationic, trinuclear sulfido-bridged aggregates containing {Pt 2PdS2} cores. [Pt2(μ-S)2(PPh 3)4] also reacts with the platinum(II) hydride complex trans-[PtHCl(PPh3)2] giving the adduct [Pt 2(μ-S)2(PPh3)4PtH(PPh 3)]+. X-ray crystal structure determinations on the complexes [Pt2(μ-S)2(PPh3) 4PdPh(PPh3)]PF6 and [Pt2(μ-S) 2(PPh3)4PtH(PPh3)]PF6 are reported, and show the expected bis μ3-sulfido aggregates with three square-planar metal centres. © 2010 Elsevier B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.ica.2010.03.068
dc.sourceScopus
dc.subjectCrystal structure
dc.subjectElectrospray mass spectrometry
dc.subjectPalladium complexes
dc.subjectPlatinum complexes
dc.subjectSulfido ligands
dc.subjectTrinuclear complexes
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/j.ica.2010.03.068
dc.description.sourcetitleInorganica Chimica Acta
dc.description.volume363
dc.description.issue11
dc.description.page2387-2393
dc.description.codenICHAA
dc.identifier.isiut000280237200004
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