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https://doi.org/10.1016/j.ica.2010.03.068
| Title: | Synthesis and characterisation of adducts of [Pt2(μ-S) 2(PPh3)4] with organo-palladium and platinum-hydride substrates | Authors: | White, B.C. Harrison, D. Henderson, W. Nicholson, B.K. Andy Hor, T.S. |
Keywords: | Crystal structure Electrospray mass spectrometry Palladium complexes Platinum complexes Sulfido ligands Trinuclear complexes |
Issue Date: | 10-Aug-2010 | Citation: | White, B.C., Harrison, D., Henderson, W., Nicholson, B.K., Andy Hor, T.S. (2010-08-10). Synthesis and characterisation of adducts of [Pt2(μ-S) 2(PPh3)4] with organo-palladium and platinum-hydride substrates. Inorganica Chimica Acta 363 (11) : 2387-2393. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ica.2010.03.068 | Abstract: | The reactions of [Pt2(μ-S)2(PPh3) 4] towards a range of palladium(II) complexes containing organometallic ligands (cyclopalladated N-donor ligands, η3- allyl, phenyl) have been explored, leading to the formation of a series of cationic, trinuclear sulfido-bridged aggregates containing {Pt 2PdS2} cores. [Pt2(μ-S)2(PPh 3)4] also reacts with the platinum(II) hydride complex trans-[PtHCl(PPh3)2] giving the adduct [Pt 2(μ-S)2(PPh3)4PtH(PPh 3)]+. X-ray crystal structure determinations on the complexes [Pt2(μ-S)2(PPh3) 4PdPh(PPh3)]PF6 and [Pt2(μ-S) 2(PPh3)4PtH(PPh3)]PF6 are reported, and show the expected bis μ3-sulfido aggregates with three square-planar metal centres. © 2010 Elsevier B.V. All rights reserved. | Source Title: | Inorganica Chimica Acta | URI: | http://scholarbank.nus.edu.sg/handle/10635/95027 | ISSN: | 00201693 | DOI: | 10.1016/j.ica.2010.03.068 |
| Appears in Collections: | Staff Publications |
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