Please use this identifier to cite or link to this item:
https://doi.org/10.1016/j.chroma.2005.07.082
Title: | Synthesis and application of mono-6-ammonium-6-deoxy-β-cyclodextrin chloride as chiral selector for capillary electrophoresis | Authors: | Tang, W. Muderawan, I.W. Ng, S.C. Chan, H.S.O. |
Keywords: | Capillary electrophoresis Enantioseparation Mono-6-ammonium-6-deoxy-β-cyclodextrin chloride Positively charged β-CD Single-isomer |
Issue Date: | 11-Nov-2005 | Citation: | Tang, W., Muderawan, I.W., Ng, S.C., Chan, H.S.O. (2005-11-11). Synthesis and application of mono-6-ammonium-6-deoxy-β-cyclodextrin chloride as chiral selector for capillary electrophoresis. Journal of Chromatography A 1094 (1-2) : 187-191. ScholarBank@NUS Repository. https://doi.org/10.1016/j.chroma.2005.07.082 | Abstract: | A facile synthetic approach for mono-6-amino-6-deoxy-β-cyclodextrin (β-CD-NH2) was proposed. Its hydroxy chloride salt, mono-6-ammonium-6-deoxy-β-cyclodextrin chloride (β-CD-NH 3Cl) was further prepared and used for the enantioseparation of various anionic and ampholytic analytes by capillary electrophoresis (CE). The effect of background electrolyte (BGE) pH and selector concentration on the enantioseparation was studied. Results showed that β-CD-NH3Cl displayed powerful chiral resolution ability towards anionic analytes. In addition, baseline separation of a standard mixture consisting of eight acids was achieved within 35 min. © 2005 Elsevier B.V. All rights reserved. | Source Title: | Journal of Chromatography A | URI: | http://scholarbank.nus.edu.sg/handle/10635/95022 | ISSN: | 00219673 | DOI: | 10.1016/j.chroma.2005.07.082 |
Appears in Collections: | Staff Publications |
Show full item record
Files in This Item:
There are no files associated with this item.
SCOPUSTM
Citations
33
checked on Jan 13, 2021
WEB OF SCIENCETM
Citations
28
checked on Jan 13, 2021
Page view(s)
52
checked on Jan 9, 2021
Google ScholarTM
Check
Altmetric
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.