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|Title:||Syntheses and structures of palladium(II) and platinum(II) complexes with tridentate (Ph2PCH2CH2CH2)2S and its arsenic analogue||Authors:||Cheng, C.R.
C-h-⋯o hydrogen bond
Six-membered chelate ring
|Issue Date:||30-Jul-1997||Citation:||Cheng, C.R.,Leung, P.-H.,Mok, K.F. (1997-07-30). Syntheses and structures of palladium(II) and platinum(II) complexes with tridentate (Ph2PCH2CH2CH2)2S and its arsenic analogue. Inorganica Chimica Acta 260 (2) : 137-143. ScholarBank@NUS Repository.||Abstract:||A series of square-planar complexes [MLCl]ClO4 (M=Pd(II), Pt(II); L=bis(3-(diphenylphosphino)propyl)sulfide (psp), bis(3-(diphenylarsino)propyl)sulfide (asa)) have been prepared and characterized. The X-ray crystal structures of two of them have been determined: [Pd(psp)Cl]ClO4, P21/c, a=12.519(2), b=15.766(2), c=16.501(2) Å, β= 105.22(1)°, Z=4; and [Pt(asa)Cl]ClO4, P2]/ c, a= 12.583 (5), b=16.007(6), c=16.549(6) Å, β= 104.89(3)°, Z=4. In both structures, there is a conformational disorder between the chair and skew-boat orientation in one of the two six-membered chelate rings. The C-H-⋯-O hydrogen bond between the hybrid ligand and the perchlorate counter ion that induces the conformational disorder is discussed.||Source Title:||Inorganica Chimica Acta||URI:||http://scholarbank.nus.edu.sg/handle/10635/95013||ISSN:||00201693|
|Appears in Collections:||Staff Publications|
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