Sulfide-bridged aggregates from the metalloligand [Pt2(μ-S) 2(PPh3)4] and β-diketonate complexes of cobalt(II) and zinc(II)

Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.ica.2005.06.082

Title:	Sulfide-bridged aggregates from the metalloligand [Pt2(μ-S) 2(PPh3)4] and β-diketonate complexes of cobalt(II) and zinc(II)
Authors:	Bridson, J.H. Henderson, W. Nicholson, B.K. Andy Hor, T.S.
Keywords:	Cobalt complexes Platinum complexes Sulfide aggregates Zinc complexes
Issue Date:	20-Jan-2006
Citation:	Bridson, J.H., Henderson, W., Nicholson, B.K., Andy Hor, T.S. (2006-01-20). Sulfide-bridged aggregates from the metalloligand [Pt2(μ-S) 2(PPh3)4] and β-diketonate complexes of cobalt(II) and zinc(II). Inorganica Chimica Acta 359 (2) : 680-684. ScholarBank@NUS Repository. https://doi.org/10.1016/j.ica.2005.06.082
Abstract:	Reaction of [Pt2(μ-S)2(PPh3) 4] with a range of zinc(II) and cobalt(II) complexes ML2, where L is a β-diketonate ligand CH3COCHCOCH3, PhCOCHCOPh, CF3COCHCOTh (Th = 2-thienyl)] permits the synthesis of adducts [Pt2(μ-S)2(PPh3) 4M(diketonate)]+, isolated as their BPh4- salts in moderate yields. The cobalt and zinc acetylacetonate complexes were characterised by single-crystal X-ray diffraction studies, which reveal isomorphous structures, with tetrahedral heterometal centres. © 2005 Elsevier B.V. All rights reserved.
Source Title:	Inorganica Chimica Acta
URI:	http://scholarbank.nus.edu.sg/handle/10635/94966
ISSN:	00201693
DOI:	10.1016/j.ica.2005.06.082
Appears in Collections:	Staff Publications

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