Please use this identifier to cite or link to this item:
Title: Structural effects of sodium cations in polynuclear, multicubane-type mixed Na-Ni complexes
Authors: Zhang, J. 
Teo, P.
Pattacini, R.
Kermagoret, A.
Welter, R.
Rogez, G.
Hor, T.S.A. 
Braunstein, P.
Keywords: Clusters compounds
Magnetic properties
Metallacrown compounds
Polynuclear complexes
Issue Date: 14-Jun-2010
Citation: Zhang, J., Teo, P., Pattacini, R., Kermagoret, A., Welter, R., Rogez, G., Hor, T.S.A., Braunstein, P. (2010-06-14). Structural effects of sodium cations in polynuclear, multicubane-type mixed Na-Ni complexes. Angewandte Chemie - International Edition 49 (26) : 4443-4446. ScholarBank@NUS Repository.
Abstract: (Figure Presented) Cubanes and beyond: Diversity and originality characterize the Ni complexes obtained from sodium (pyridine-2-yl)methanolate. The ligand/metal ratio and the presence of Na+ are key parameters to explain the formation of Ni4Na3, Ni6Na, or Ni7 polynuclear complexes with magnetically interacting centers. Such observations are relevant to the possible in situ formation of unexpected and possibly overlooked active species in catalytic reactions. © 2010 WIley-VCH Verlag GmbH & Co. KGaA, Weinheim.
Source Title: Angewandte Chemie - International Edition
ISSN: 14337851
DOI: 10.1002/anie.201001412
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Google ScholarTM



Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.