Solvent-dependent networking of O2S2-macrocycle with silver perchlorate into one-and two-dimensional coordination polymers

Please use this identifier to cite or link to this item: https://doi.org/10.1021/cg901335w

Title:	Solvent-dependent networking of O2S2-macrocycle with silver perchlorate into one-and two-dimensional coordination polymers
Authors:	Lee, S.Y. Jung, J.H. Vittal, J.J. Lee, S.S.
Issue Date:	3-Mar-2010
Citation:	Lee, S.Y., Jung, J.H., Vittal, J.J., Lee, S.S. (2010-03-03). Solvent-dependent networking of O2S2-macrocycle with silver perchlorate into one-and two-dimensional coordination polymers. Crystal Growth and Design 10 (3) : 1033-1036. ScholarBank@NUS Repository. https://doi.org/10.1021/cg901335w
Abstract:	The solvent-dependent double-stranded one-dimensional (1-D) coordination polymer [Ag2L2(C104)2]n (1) and another 1-D polymer {[Ag2L2(CH3CN)] -2ClO4}Jn (2a) with the shape of a cut of tube along the long axis were obtained in the reactions of a 16membered O2S 2-macrocycle L with silver(I) Perchlorate in DCM/MeOH and CH 3CN, respectively. Time-dependent crystallization experiments unambiguously show that 2a is a kinetic product and transforms into a thermodynamically more stable [AgLC104]n(2b) with a two-dimensional square-grid structure. © 2010 American Chemical Soc.
Source Title:	Crystal Growth and Design
URI:	http://scholarbank.nus.edu.sg/handle/10635/94847
ISSN:	15287483
DOI:	10.1021/cg901335w
Appears in Collections:	Staff Publications

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