Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.200503408
Title: Self-organization of spherical, core-shell palladium aggregates by laser-induced and thermal decomposition of [Pd(PPh3)4]
Authors: Ye, E. 
Tan, H.
Li, S.
Fan, W.Y. 
Keywords: Aggregation
Nanostructures
Palladium
Photochemistry
Self-assembly
Issue Date: 6-Feb-2006
Citation: Ye, E., Tan, H., Li, S., Fan, W.Y. (2006-02-06). Self-organization of spherical, core-shell palladium aggregates by laser-induced and thermal decomposition of [Pd(PPh3)4]. Angewandte Chemie - International Edition 45 (7) : 1120-1123. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.200503408
Abstract: (Figure Presented) Metal in the middle: Uniform, spherical, core-shell aggregates (100 ± 20 nm; see picture) are obtained by photodecomposition of [Pd(PPh3)4] to form the metal core, followed by aggregation of smaller Pd nanocrystals and free phosphanes, produced by thermal decomposition of the remaining precursor, around this core. Prolonged irradiation or thermal decomposition alone yields only the core structure or the shell structure, respectively. This enables the nanoparticle structure to be tuned. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
Source Title: Angewandte Chemie - International Edition
URI: http://scholarbank.nus.edu.sg/handle/10635/94787
ISSN: 14337851
DOI: 10.1002/anie.200503408
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