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https://doi.org/10.1007/s10876-007-0138-5
| Title: | Reduced overlap population analysis for triosmium clusters | Authors: | Morrison, E.C. Leong, W.K. Tan, J. |
Keywords: | Alkoxy Cluster EHMO Osmium ROP |
Issue Date: | Sep-2007 | Citation: | Morrison, E.C., Leong, W.K., Tan, J. (2007-09). Reduced overlap population analysis for triosmium clusters. Journal of Cluster Science 18 (3) : 753-763. ScholarBank@NUS Repository. https://doi.org/10.1007/s10876-007-0138-5 | Abstract: | The use of reduced overlap population (ROP) analysis from EHMO calculations as a means to gauge the presence of metal-metal bonds in triosmium clusters is examined. A number of triosmium clusters containing bridging ligands have been used as test cases, including the bis-ethoxy bridged cluster Os 3(μ-OEt)2(CO)10, 1b, and some of its group 15 derivatives Os3(μ-OEt)2(CO)9(EPh 3), 2. These latter clusters are newly synthesized and have been characterized completely, including by single-crystal X-ray crystallographic studies. © 2007 Springer Science+Business Media, LLC. | Source Title: | Journal of Cluster Science | URI: | http://scholarbank.nus.edu.sg/handle/10635/94700 | ISSN: | 10407278 | DOI: | 10.1007/s10876-007-0138-5 |
| Appears in Collections: | Staff Publications |
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