Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2005.03.001
DC FieldValue
dc.titleReactivity of [CpCr(CO)3]2 towards thione (CS) moieties in some sulfur-containing substrates
dc.contributor.authorNg, V.W.L.
dc.contributor.authorKuan, S.L.
dc.contributor.authorWeng, Z.
dc.contributor.authorLeong, W.K.
dc.contributor.authorVittal, J.J.
dc.contributor.authorKoh, L.L.
dc.contributor.authorTan, G.K.
dc.contributor.authorGoh, L.Y.
dc.date.accessioned2014-10-16T08:38:58Z
dc.date.available2014-10-16T08:38:58Z
dc.date.issued2005-04-29
dc.identifier.citationNg, V.W.L., Kuan, S.L., Weng, Z., Leong, W.K., Vittal, J.J., Koh, L.L., Tan, G.K., Goh, L.Y. (2005-04-29). Reactivity of [CpCr(CO)3]2 towards thione (CS) moieties in some sulfur-containing substrates. Journal of Organometallic Chemistry 690 (9) : 2360-2369. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2005.03.001
dc.identifier.issn0022328X
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/94691
dc.description.abstractThe reaction of [CpCr(CO)3]2 (Cp = η5-C5H5) (1) with 1 mol equivalent of 2,5-dimercapto-1,3,4-thiadiazole (DMcTH2) at ambient temperature led to the isolation of a reddish-brown crystalline solid of CpCr(CO) 3(η1-DMcTH) (5) and a green solid of CpCr(CO) 3H (2) in yields of ca. 28% and 30%, respectively, along with some [CpCr(CO)2]2 (3) and [CpCr(CO)2]2S (4). The reaction of 1 with 1 mol equivalent of vinylene trithiocarbonate (SCS(CH)2S) (VTTC) at 90 °C led to the isolation of a red crystalline solid of CpCr(CO)2(η2-SCHSC 2H2) (6) in ca. 15% yield while the reaction of 1 with isopropylxanthic disulfide ((CH3)2CHOCS2) 2 resulted in the formation of CpCr(CO)2(η 2-S2COCH(CH3)2) (8) in ca. 80% yield. The complexes 5, 6 and 8 have been determined by single crystal X-ray diffraction analysis. © 2005 Elsevier B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jorganchem.2005.03.001
dc.sourceScopus
dc.subject2,5-Dimercapto-1,3,4-thiadiazole
dc.subjectCyclopentadienylchromium
dc.subjectIsopropylxanthic disulfide
dc.subjectVinylene trithiocarbonate
dc.subjectX-ray crystal structures
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/j.jorganchem.2005.03.001
dc.description.sourcetitleJournal of Organometallic Chemistry
dc.description.volume690
dc.description.issue9
dc.description.page2360-2369
dc.description.codenJORCA
dc.identifier.isiut000229456200022
Appears in Collections:Staff Publications

Show simple item record
Files in This Item:
There are no files associated with this item.

SCOPUSTM   
Citations

9
checked on Oct 22, 2019

WEB OF SCIENCETM
Citations

6
checked on Oct 22, 2019

Page view(s)

51
checked on Oct 12, 2019

Google ScholarTM

Check

Altmetric


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.