Please use this identifier to cite or link to this item:
https://scholarbank.nus.edu.sg/handle/10635/94662
| Title: | Reaction of pentafluoronitrosobenzene with [Os3H(μ-H) (CO)10(MPh3) ](M = P, As, Sb): Synthesis and X-ray structure of [Os3(μ-H) (CO) 10(PPh3)(ONC6F4O) | Authors: | Ang, H.G. Kwik, W.L. Ong, K.K. |
Keywords: | Osmium Synthesis |
Issue Date: | 12-Jul-1994 | Citation: | Ang, H.G.,Kwik, W.L.,Ong, K.K. (1994-07-12). Reaction of pentafluoronitrosobenzene with [Os3H(μ-H) (CO)10(MPh3) ](M = P, As, Sb): Synthesis and X-ray structure of [Os3(μ-H) (CO) 10(PPh3)(ONC6F4O). Journal of Organometallic Chemistry 474 (1-2) : 149-152. ScholarBank@NUS Repository. | Abstract: | The pentafluoronitrosobenzene C6F5NO has been shown from infrared spectral, 19F NMR spectral and single-crystal X-ray diffraction studies to undergo oxidation at the para-position upon reaction with [OS3H(μ-H)(CO)10(PPh3)] to afford [OS3(μ-H)(CO)10(PPh3)(ONC6F4O)](I). The arsenic- and stibine- analogues of I [(OS3)(μ-H)(CO)10(MPh3)(XONC6F40)l (M = As, Sb)) were also isolated. © 1994. | Source Title: | Journal of Organometallic Chemistry | URI: | http://scholarbank.nus.edu.sg/handle/10635/94662 | ISSN: | 0022328X |
| Appears in Collections: | Staff Publications |
Show full item record
Files in This Item:
There are no files associated with this item.
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.