Please use this identifier to cite or link to this item:
https://scholarbank.nus.edu.sg/handle/10635/94661
DC Field | Value | |
---|---|---|
dc.title | Reaction of pentafluoronitrosobenzene with [Os3(CO)11(CH3CN)] and high-performance liquid chromatographic separation of... | |
dc.contributor.author | Ang, H.G. | |
dc.contributor.author | Kwik, W.L. | |
dc.contributor.author | Ong, K.K. | |
dc.date.accessioned | 2014-10-16T08:38:39Z | |
dc.date.available | 2014-10-16T08:38:39Z | |
dc.date.issued | 1993-01 | |
dc.identifier.citation | Ang, H.G.,Kwik, W.L.,Ong, K.K. (1993-01). Reaction of pentafluoronitrosobenzene with [Os3(CO)11(CH3CN)] and high-performance liquid chromatographic separation of.... Journal of Fluorine Chemistry 60 (1) : 43-48. ScholarBank@NUS Repository. | |
dc.identifier.issn | 00221139 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/94661 | |
dc.description.abstract | Title full: Reaction of pentafluoronitrosobenzene with [Os3(CO)11(CH3CN)] and high-performance liquid chromatographic separation of [Os3(CO)11(μ-ONC6F5)], [Os3(CO)9(μ3-NC6F5 )2], [Os3(CO)11(CH3 CN)] and Os3(CO)12. Reaction of pentafluoronitrosobenzene with [Os3(CO)11(CH3CN)] in THF at room temperature yields a new triosmium cluster, [Os3(CO)11(μ-ONC6F5)] (I), where the pentafluorophenylnitroso ligand has been shown by X-ray crystallography to adopt an unusual bonding mode, with its nitrogen bridging two non-bonded osmium atoms and the oxygen atom bonded to one of the osmium atoms. The separation of [Os3(CO)11(μ-ONC6F5)] (I), [Os3(CO)9(μ3-NC6F 5)2] (II) and their parent triosmium clusters, i.e. [Os3(CO)11-(CH3CN)] and Os3(CO)12, by high-performance liquid chromatography is also described. © 1993. | |
dc.source | Scopus | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.sourcetitle | Journal of Fluorine Chemistry | |
dc.description.volume | 60 | |
dc.description.issue | 1 | |
dc.description.page | 43-48 | |
dc.identifier.isiut | NOT_IN_WOS | |
Appears in Collections: | Staff Publications |
Show simple item record
Files in This Item:
There are no files associated with this item.
Google ScholarTM
Check
Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.