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|Title:||Pore Size Engineering on MCM-41: Selectivity Tuning of Heterogenized AlCl3 for the Synthesis of Linear Alkyl Benzenes||Authors:||Hu, X.
|Issue Date:||25-Oct-2000||Citation:||Hu, X., Foo, M.L., Chuah, G.K., Jaenicke, S. (2000-10-25). Pore Size Engineering on MCM-41: Selectivity Tuning of Heterogenized AlCl3 for the Synthesis of Linear Alkyl Benzenes. Journal of Catalysis 195 (2) : 412-415. ScholarBank@NUS Repository. https://doi.org/10.1006/jcat.2000.2965||Abstract:||AlCl3 has been successfully immobilized on MCM-41 mesoporous silica of different pore sizes to form a novel shape-selective catalyst for the Friedel-Crafts alkylation of benzene with long-chain olefins (linear 1-olefins with a chain length of 6 to 16 carbon atoms). The selectivity toward the monoalkylated product is strongly influenced by the pore size of the carrier material. This demonstrates the opportunities offered by the micelle-templating method to tailor shape-selective catalysts for reactions with bigger molecules. © 2000 Academic Press.||Source Title:||Journal of Catalysis||URI:||http://scholarbank.nus.edu.sg/handle/10635/94579||ISSN:||00219517||DOI:||10.1006/jcat.2000.2965|
|Appears in Collections:||Staff Publications|
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