Please use this identifier to cite or link to this item: https://doi.org/10.1016/S0040-4039(03)00347-2
Title: Mono(6A-N-allylamino-6A-deoxy)perphenylcarbamoylated β-cyclodextrin: Synthesis and application as a chiral stationary phase for HPLC
Authors: Lai, X.
Ng, S.-C. 
Keywords: Chiral stationary phases
Cyclodextrin
Enantioseparation
Hydrosilylation
Issue Date: 24-Mar-2003
Citation: Lai, X., Ng, S.-C. (2003-03-24). Mono(6A-N-allylamino-6A-deoxy)perphenylcarbamoylated β-cyclodextrin: Synthesis and application as a chiral stationary phase for HPLC. Tetrahedron Letters 44 (13) : 2657-2660. ScholarBank@NUS Repository. https://doi.org/10.1016/S0040-4039(03)00347-2
Abstract: A novel cyclodextrin derivative: mono(6A-N-allylamino-6A-deoxy)perphenylcarbamoylated β-cyclodextrin was synthesized. Hydrosilylation with (EtO)3SiH and then reaction of the reactive siloxane with pristine silica gel afforded a facile entry into a durable, structurally well-defined chiral stationary phase capable of enantioseparation of a variety of racemic drugs. © 2003 Elsevier Science Ltd. All rights reserved.
Source Title: Tetrahedron Letters
URI: http://scholarbank.nus.edu.sg/handle/10635/94319
ISSN: 00404039
DOI: 10.1016/S0040-4039(03)00347-2
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