Please use this identifier to cite or link to this item: https://doi.org/10.1007/BF00255201
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dc.titleMicellar polymerization of surfactants - Sodium 6-acrylamidocaproate and sodium 11-(N-methyl acrylamido)undecanoate
dc.contributor.authorYeoh, K.W.
dc.contributor.authorChew, C.H.
dc.contributor.authorGan, L.M.
dc.contributor.authorKoh, L.L.
dc.date.accessioned2014-10-16T08:33:34Z
dc.date.available2014-10-16T08:33:34Z
dc.date.issued1989-08
dc.identifier.citationYeoh, K.W., Chew, C.H., Gan, L.M., Koh, L.L. (1989-08). Micellar polymerization of surfactants - Sodium 6-acrylamidocaproate and sodium 11-(N-methyl acrylamido)undecanoate. Polymer Bulletin 22 (2) : 123-129. ScholarBank@NUS Repository. https://doi.org/10.1007/BF00255201
dc.identifier.issn01700839
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/94225
dc.description.abstractMicelle-forming sodium 6-acrylamidocaproate (Na 6-AAC) and sodium 11-(N-methyl acrylamido)undecanoate (Na 11-MAAU) were synthesized and polymerized in aqueous solutions. The polymerization was very rapid and it followed first-order kinetics with respect to the monomer and one-half order to K2S2O8. The activation energy for the polymerization of Na 11-MAAU (62.3 kJ/mol) was much lower than that for Na 6-AAC (98.1 kJ/mol). The -Mw. for the former was around one million and it was only one-third of that for the latter. Their MWD (-Mw/-Mn ∼- 1.5) are relatively narrow. The relationships between intrinsic viscosity [η]o and -Mw for these polysurfactants have also been established. © 1989 Springer-Verlag.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1007/BF00255201
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1007/BF00255201
dc.description.sourcetitlePolymer Bulletin
dc.description.volume22
dc.description.issue2
dc.description.page123-129
dc.description.codenPOBUD
dc.identifier.isiutA1989AM44300004
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