Please use this identifier to cite or link to this item: https://doi.org/10.1039/FT9918701685
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dc.titleHe I and He II photoelectron spectra of isomeric nitropropenes
dc.contributor.authorChin, W.S.
dc.contributor.authorMok, C.Y.
dc.contributor.authorHuang, H.H.
dc.date.accessioned2014-10-16T08:29:56Z
dc.date.available2014-10-16T08:29:56Z
dc.date.issued1991
dc.identifier.citationChin, W.S., Mok, C.Y., Huang, H.H. (1991). He I and He II photoelectron spectra of isomeric nitropropenes. Journal of the Chemical Society, Faraday Transactions 87 (11) : 1685-1689. ScholarBank@NUS Repository. https://doi.org/10.1039/FT9918701685
dc.identifier.issn09565000
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/93914
dc.description.abstractThe He II photoelectron spectra of 1-, 2- and 3-nitropropene have been recorded and compared with the corresponding He I spectra. The variation in relative He I/He II band intensities allows unequivocal classification of bands into those associated with orbitals of the nitro group and those with orbitals of the hydrocarbon moiety. Band assignment is also aided by observed vibrational structure, band shape and SCF MO calculations. The variation of the relative energies of the orbitals πC=C, n0 +, n0 + and π2 among the isomers is discussed in terms of inductive, hyperconjugation and resonance effects.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1039/FT9918701685
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1039/FT9918701685
dc.description.sourcetitleJournal of the Chemical Society, Faraday Transactions
dc.description.volume87
dc.description.issue11
dc.description.page1685-1689
dc.identifier.isiutA1991FR36500003
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