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|Title:||Gold(III) thiosalicylate complexes containing cycloaurated 2-arylpyridine, 2-anilinopyridine and 2-benzylpyridine ligands||Authors:||Henderson, W.
|Issue Date:||10-Aug-2001||Citation:||Henderson, W., Nicholson, B.K., Faville, S.J., Fan, D., Ranford, J.D. (2001-08-10). Gold(III) thiosalicylate complexes containing cycloaurated 2-arylpyridine, 2-anilinopyridine and 2-benzylpyridine ligands. Journal of Organometallic Chemistry 631 (1-2) : 41-46. ScholarBank@NUS Repository. https://doi.org/10.1016/S0022-328X(01)00987-1||Abstract:||Reactions of the gold(III) dichloride complexes [(N_C)AuCl2] ((N_C)=cycloaurated 2-phenylpyridine, 2-(p-tolyl)pyridine, 2-anilinopyridine or 2-benzylpyridine) with thiosalicylic acid (2-mercaptobenzoic acid, HSC6H4CO2H) and base gives a series of gold(III) thiosalicylate complexes [(N_C)Au(SC6H4CO2)]. A crystal structure determination on the 2-p-tolylpyridine derivative is reported, confirming the presence of a chelating thiosalicylate ligand, with the tolyl and thiolate groups mutually cis, together with a highly puckered gold-thiosalicylate moiety, and a twisted carboxylate group. The activity of the thiosalicylate complexes against P388 leukaemia cells has been determined. © 2001 Elsevier Science B.V.||Source Title:||Journal of Organometallic Chemistry||URI:||http://scholarbank.nus.edu.sg/handle/10635/93896||ISSN:||0022328X||DOI:||10.1016/S0022-328X(01)00987-1|
|Appears in Collections:||Staff Publications|
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