Please use this identifier to cite or link to this item: https://doi.org/10.1021/jp065652
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dc.titleDirect functionalization of the hydroxyl group of the 6-mercapto-1-hexanol (MCH) ligand attached to gold nanoclusters
dc.contributor.authorTan, H.
dc.contributor.authorZhan, T.
dc.contributor.authorFan, W.Y.
dc.date.accessioned2014-10-16T08:26:15Z
dc.date.available2014-10-16T08:26:15Z
dc.date.issued2006-11-02
dc.identifier.citationTan, H., Zhan, T., Fan, W.Y. (2006-11-02). Direct functionalization of the hydroxyl group of the 6-mercapto-1-hexanol (MCH) ligand attached to gold nanoclusters. Journal of Physical Chemistry B 110 (43) : 21690-21693. ScholarBank@NUS Repository. https://doi.org/10.1021/jp065652
dc.identifier.issn15206106
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/93605
dc.description.abstractAu-MCH nanoclusters of (1.5 ± 0.3) nm diameter (MCH = 6-mercapto-1-hexanol, HS-(CH2)6-OH) have been prepared and characterized by Transmission Electron Microscopy (TEM), UV-visible, Nuclear Magnetic Resonance (NMR), Fourier Transform Infrared (FTIR) absorption spectroscopies, X-ray Powder Diffraction (XRD), and Thermogravimetric Analysis (TGA). While in nanocluster form dispersed in solution, the OH terminal group of the MCH ligand has been directly functionalized through small organic molecule reactions in near-quantitative yield (>90%) to generate ester, carbamate, carboxylic acid, nitrite, and aldehyde groups, as recorded by FTIR spectroscopy. The size of the final gold nanocluster derivative is preserved for all the reactions studied here. © 2006 American Chemical Society.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1021/jp065652
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1021/jp065652
dc.description.sourcetitleJournal of Physical Chemistry B
dc.description.volume110
dc.description.issue43
dc.description.page21690-21693
dc.description.codenJPCBF
dc.identifier.isiut000241553500046
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