Please use this identifier to cite or link to this item: https://doi.org/10.1039/FT9918700917
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dc.titleDetection of chlorophosphaethyne, Cl-C≡P, by photoelectron spectroscopy
dc.contributor.authorDennis, T.J.
dc.contributor.authorFirth, S.
dc.contributor.authorKroto, H.W.
dc.contributor.authorMatti, G.Y.
dc.contributor.authorMok, C.
dc.contributor.authorSuffolk, R.J.
dc.contributor.authorWalton, D.R.M.
dc.date.accessioned2014-10-16T08:25:27Z
dc.date.available2014-10-16T08:25:27Z
dc.date.issued1991
dc.identifier.citationDennis, T.J., Firth, S., Kroto, H.W., Matti, G.Y., Mok, C., Suffolk, R.J., Walton, D.R.M. (1991). Detection of chlorophosphaethyne, Cl-C≡P, by photoelectron spectroscopy. Journal of the Chemical Society, Faraday Transactions 87 (7) : 917-920. ScholarBank@NUS Repository. https://doi.org/10.1039/FT9918700917
dc.identifier.issn09565000
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/93536
dc.description.abstractThe new molecule chlorophosphaethyne, Cl-C≡P, has been produced by flow thermolysis of trichloromethylphosphonous dichloride, Cl3CPCl2, over granulated zinc at 530 °C and its photoelectron spectrum has been recorded. All four bands expected below 21 eV have been detected and the first vertical ionization energy at 10.10 eV is assigned to the degenerate 4π orbital. The assignments are supported by ab initio SCF calculations.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1039/FT9918700917
dc.sourceScopus
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1039/FT9918700917
dc.description.sourcetitleJournal of the Chemical Society, Faraday Transactions
dc.description.volume87
dc.description.issue7
dc.description.page917-920
dc.identifier.isiutA1991FG05200001
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