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Title: Detection of chlorophosphaethyne, Cl-C≡P, by photoelectron spectroscopy
Authors: Dennis, T.J.
Firth, S.
Kroto, H.W.
Matti, G.Y.
Mok, C. 
Suffolk, R.J.
Walton, D.R.M.
Issue Date: 1991
Citation: Dennis, T.J., Firth, S., Kroto, H.W., Matti, G.Y., Mok, C., Suffolk, R.J., Walton, D.R.M. (1991). Detection of chlorophosphaethyne, Cl-C≡P, by photoelectron spectroscopy. Journal of the Chemical Society, Faraday Transactions 87 (7) : 917-920. ScholarBank@NUS Repository.
Abstract: The new molecule chlorophosphaethyne, Cl-C≡P, has been produced by flow thermolysis of trichloromethylphosphonous dichloride, Cl3CPCl2, over granulated zinc at 530 °C and its photoelectron spectrum has been recorded. All four bands expected below 21 eV have been detected and the first vertical ionization energy at 10.10 eV is assigned to the degenerate 4π orbital. The assignments are supported by ab initio SCF calculations.
Source Title: Journal of the Chemical Society, Faraday Transactions
ISSN: 09565000
DOI: 10.1039/FT9918700917
Appears in Collections:Staff Publications

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