Please use this identifier to cite or link to this item: https://doi.org/10.1002/anie.200600724
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dc.titleCyclopentadienylchromium complexes of 1,2,3,5-dithiadiazolyls: η2 π complexes of cyclic sulfur-nitrogen compounds
dc.contributor.authorLau, H.F.
dc.contributor.authorNg, V.W.L.
dc.contributor.authorKoh, L.L.
dc.contributor.authorTan, G.K.
dc.contributor.authorGoh, L.Y.
dc.contributor.authorRoemmele, T.L.
dc.contributor.authorSeagrave, S.D.
dc.contributor.authorBoeré, R.T.
dc.date.accessioned2014-10-16T08:25:14Z
dc.date.available2014-10-16T08:25:14Z
dc.date.issued2006-07-03
dc.identifier.citationLau, H.F., Ng, V.W.L., Koh, L.L., Tan, G.K., Goh, L.Y., Roemmele, T.L., Seagrave, S.D., Boeré, R.T. (2006-07-03). Cyclopentadienylchromium complexes of 1,2,3,5-dithiadiazolyls: η2 π complexes of cyclic sulfur-nitrogen compounds. Angewandte Chemie - International Edition 45 (27) : 4498-4501. ScholarBank@NUS Repository. https://doi.org/10.1002/anie.200600724
dc.identifier.issn14337851
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/93517
dc.description.abstract(Figure Presented) Diamagnetic π complexes are formed in the reaction between [{CpCr(CO)3}2] and dithiadiazolyl dimers [S 2N2CR]2 (R = substituted phenyl rings) in which the heterocycles are η2-coordinated to the metal in endo (depicted) or exo fashion. The isomers interconvert in solution at room temperature. These complexes are remarkable for retaining intact the S-S bonds of the dithiadiazolyl radicals (C gray, H white, O red, Cr purple, S yellow, N blue, Cl green). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1002/anie.200600724
dc.sourceScopus
dc.subjectChromium
dc.subjectCyclopentadienyl ligands
dc.subjectPi interactions
dc.subjectRadicals
dc.subjectS ligands
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1002/anie.200600724
dc.description.sourcetitleAngewandte Chemie - International Edition
dc.description.volume45
dc.description.issue27
dc.description.page4498-4501
dc.description.codenACIEA
dc.identifier.isiut000238927000020
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