Please use this identifier to cite or link to this item:
https://doi.org/10.1021/om1005947
DC Field | Value | |
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dc.title | CpMn(CO)3-catalyzed photoconversion of thiols into disulfides and dihydrogen | |
dc.contributor.author | Tan, K.Y.D. | |
dc.contributor.author | Kee, J.W. | |
dc.contributor.author | Fan, W.Y. | |
dc.date.accessioned | 2014-10-16T08:24:00Z | |
dc.date.available | 2014-10-16T08:24:00Z | |
dc.date.issued | 2010-10-25 | |
dc.identifier.citation | Tan, K.Y.D., Kee, J.W., Fan, W.Y. (2010-10-25). CpMn(CO)3-catalyzed photoconversion of thiols into disulfides and dihydrogen. Organometallics 29 (20) : 4459-4463. ScholarBank@NUS Repository. https://doi.org/10.1021/om1005947 | |
dc.identifier.issn | 02767333 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/93408 | |
dc.description.abstract | The UV photolysis of CpMn(CO)3 with thiols at room temperature effected the following catalytic transformation: 2 RSH → R 2S2 + H2. This reaction is a cleaner and greener way toward making disulfides, as it produces dihydrogen as the only side-product. The manganese system exhibits high chemoselectivity as the transformation proceeds efficiently even in the presence of numerous functional groups. A manganese dicarbonyl complex, CpMn(CO)2RSH, and cyclopentadiene have also been detected using FTIR and NMR spectroscopic techniques, respectively. Based on our experimental data, a mechanism has been proposed to account for the catalysis. © 2010 American Chemical Society. | |
dc.description.uri | http://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1021/om1005947 | |
dc.source | Scopus | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.doi | 10.1021/om1005947 | |
dc.description.sourcetitle | Organometallics | |
dc.description.volume | 29 | |
dc.description.issue | 20 | |
dc.description.page | 4459-4463 | |
dc.description.coden | ORGND | |
dc.identifier.isiut | 000282930900010 | |
Appears in Collections: | Staff Publications |
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