Please use this identifier to cite or link to this item: https://doi.org/10.1016/j.jorganchem.2003.12.020
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dc.titleChloride substitution of [CpRu(dppf)Cl] with sulfur-containing ligands
dc.contributor.authorLu, X.L.
dc.contributor.authorVittal, J.J.
dc.contributor.authorTiekink, E.R.T.
dc.contributor.authorGoh, L.Y.
dc.contributor.authorHor, T.S.A.
dc.date.accessioned2014-10-16T08:22:50Z
dc.date.available2014-10-16T08:22:50Z
dc.date.issued2004-05-01
dc.identifier.citationLu, X.L., Vittal, J.J., Tiekink, E.R.T., Goh, L.Y., Hor, T.S.A. (2004-05-01). Chloride substitution of [CpRu(dppf)Cl] with sulfur-containing ligands. Journal of Organometallic Chemistry 689 (9) : 1444-1451. ScholarBank@NUS Repository. https://doi.org/10.1016/j.jorganchem.2003.12.020
dc.identifier.issn0022328X
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/93306
dc.description.abstractThe reactions of CpRu(dppf)Cl (1) with the sulfur-containing ligands, thiophenol HSPh, 2-mercaptopyridine C5H4N(SH), thiourea SC(NH2)2, vinylene trithiocarbonate SCS(CH)2S and ethylene trithiocarbonate SCS(CH2)2S, yielded chloro-substituted derivatives, viz. the mono-ruthenium(II) complexes CpRu(dppf)(SPh) (2), [CpRu(dppf)(SC5H4NH)]BPh4 (3)BPh4, [CpRu(dppf)(SC(NH2)2] PF6 (4)PF6, [CpRu(dppf)(SCS(CH)2S)]Cl (5)Cl and [CpRu(dppf)(SCS(CH2)2S)]Cl (6)Cl, respectively. Treatment of 1 with AuCl(SMe2) in the presence of NH4PF6 gave [(CpRu(dppf)(SMe2)] PF6 (7)PF6. The reaction of 1 or 6 with SnCl2 resulted in cleavage of chloro and dithiocarbonate ligands, respectively, to give CpRu(dppf)SnCl3 (8). All complexes were spectroscopically characterized and the structures of 2 and cationic complexes 4-7 were determined by single-crystal diffraction analyses. © 2004 Elsevier B.V. All rights reserved.
dc.description.urihttp://libproxy1.nus.edu.sg/login?url=http://dx.doi.org/10.1016/j.jorganchem.2003.12.020
dc.sourceScopus
dc.subject1,1′-Bis(diphenylphosphino)ferrocene
dc.subjectCrystal structures
dc.subjectCyclopentadienyl
dc.subjectRuthenium
dc.subjectSulfur-containing ligands
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.doi10.1016/j.jorganchem.2003.12.020
dc.description.sourcetitleJournal of Organometallic Chemistry
dc.description.volume689
dc.description.issue9
dc.description.page1444-1451
dc.description.codenJORCA
dc.identifier.isiut000221159500002
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