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https://scholarbank.nus.edu.sg/handle/10635/93294
DC Field | Value | |
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dc.title | Chemistry of functionalized thiolates: Syntheses and structures of neutral, monomeric [Zn(SC6H4X-4)2(N-N)], where X=H, NH2 and OH, and (N-N)=nitrogen bases 2,2′-bpy, phen and tmen | |
dc.contributor.author | Anjali, K.S. | |
dc.contributor.author | Sampanthar, J.T. | |
dc.contributor.author | Vittal, J.J. | |
dc.date.accessioned | 2014-10-16T08:22:41Z | |
dc.date.available | 2014-10-16T08:22:41Z | |
dc.date.issued | 1999-11-15 | |
dc.identifier.citation | Anjali, K.S.,Sampanthar, J.T.,Vittal, J.J. (1999-11-15). Chemistry of functionalized thiolates: Syntheses and structures of neutral, monomeric [Zn(SC6H4X-4)2(N-N)], where X=H, NH2 and OH, and (N-N)=nitrogen bases 2,2′-bpy, phen and tmen. Inorganica Chimica Acta 295 (1) : 9-17. ScholarBank@NUS Repository. | |
dc.identifier.issn | 00201693 | |
dc.identifier.uri | http://scholarbank.nus.edu.sg/handle/10635/93294 | |
dc.description.abstract | Six neutral monomers of the type [Zn(SC6H4X-4)2(N-N)] (where X=H, NH2, OH; (N-N)=tetramethylethylenediamine (tmen); 2,2′-bipyridyl (bpy) and 1,10-phenanthroline (phen)) have been synthesized in quantitative yield by reacting bis(4-substituted benzenethiolato)zinc(II) with an equimolar amount of the dinitrogen bases. The crystal and molecular structures of all the compounds were determined by X-ray crystallography. A simple neutral compound [Zn(SPh)2(bpy)] was also prepared for comparison. The compounds show some interesting X-HS (where X=O or N) hydrogen bonding pattern in the solid state. © 1999 Elsevier Science S.A. | |
dc.source | Scopus | |
dc.subject | Crystal structures | |
dc.subject | Thiolate complexes | |
dc.subject | Zinc complexes | |
dc.type | Article | |
dc.contributor.department | CHEMISTRY | |
dc.description.sourcetitle | Inorganica Chimica Acta | |
dc.description.volume | 295 | |
dc.description.issue | 1 | |
dc.description.page | 9-17 | |
dc.description.coden | ICHAA | |
dc.identifier.isiut | NOT_IN_WOS | |
Appears in Collections: | Staff Publications |
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