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|Title:||Chemistry of functionalized thiolates: Syntheses and structures of neutral, monomeric [Zn(SC6H4X-4)2(N-N)], where X=H, NH2 and OH, and (N-N)=nitrogen bases 2,2′-bpy, phen and tmen||Authors:||Anjali, K.S.
|Issue Date:||15-Nov-1999||Citation:||Anjali, K.S.,Sampanthar, J.T.,Vittal, J.J. (1999-11-15). Chemistry of functionalized thiolates: Syntheses and structures of neutral, monomeric [Zn(SC6H4X-4)2(N-N)], where X=H, NH2 and OH, and (N-N)=nitrogen bases 2,2′-bpy, phen and tmen. Inorganica Chimica Acta 295 (1) : 9-17. ScholarBank@NUS Repository.||Abstract:||Six neutral monomers of the type [Zn(SC6H4X-4)2(N-N)] (where X=H, NH2, OH; (N-N)=tetramethylethylenediamine (tmen); 2,2′-bipyridyl (bpy) and 1,10-phenanthroline (phen)) have been synthesized in quantitative yield by reacting bis(4-substituted benzenethiolato)zinc(II) with an equimolar amount of the dinitrogen bases. The crystal and molecular structures of all the compounds were determined by X-ray crystallography. A simple neutral compound [Zn(SPh)2(bpy)] was also prepared for comparison. The compounds show some interesting X-HS (where X=O or N) hydrogen bonding pattern in the solid state. © 1999 Elsevier Science S.A.||Source Title:||Inorganica Chimica Acta||URI:||http://scholarbank.nus.edu.sg/handle/10635/93294||ISSN:||00201693|
|Appears in Collections:||Staff Publications|
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