Please use this identifier to cite or link to this item:
Title: Bisphenylbis[tetracarbonyl(hydrido)osmio]-germane, Ph2Ge[Os(CO)4H]2
Authors: Leong, W.K. 
Einstein, F.W.B.
Pomeroy, R.K.
Issue Date: 15-Jan-1997
Citation: Leong, W.K.,Einstein, F.W.B.,Pomeroy, R.K. (1997-01-15). Bisphenylbis[tetracarbonyl(hydrido)osmio]-germane, Ph2Ge[Os(CO)4H]2. Acta Crystallographica Section C: Crystal Structure Communications 53 (1) : 22-24. ScholarBank@NUS Repository.
Abstract: The title compound, octacarbonyl-1κ4C,2κ 4C-dihydrido-1κH,2κH-bis(phenyl-3κC) germaniumdiosmium(2 Ge-Os), [Os2(H)2(CO)8{Ge(C6H 5)2}], is the first cluster containing a single Os-E-Os (E = Ge, Sn or Pb) chain to be structurally characterized. The molecule possesses approximate C2 symmetry. The Os-Ge-Os metal chain is bent and the Os-Ge bonds [2.599(2) and 2.614 (2) Å] are the longest yet known.
Source Title: Acta Crystallographica Section C: Crystal Structure Communications
ISSN: 01082701
Appears in Collections:Staff Publications

Show full item record
Files in This Item:
There are no files associated with this item.

Page view(s)

checked on Oct 12, 2019

Google ScholarTM


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.