Please use this identifier to cite or link to this item: https://scholarbank.nus.edu.sg/handle/10635/93160
DC FieldValue
dc.titleAxial and equatorial isomers in an isonitrile-substituted osmium-antimony cluster
dc.contributor.authorChen, G.
dc.contributor.authorLeong, W.K.
dc.date.accessioned2014-10-16T08:21:06Z
dc.date.available2014-10-16T08:21:06Z
dc.date.issued1999-02-18
dc.identifier.citationChen, G.,Leong, W.K. (1999-02-18). Axial and equatorial isomers in an isonitrile-substituted osmium-antimony cluster. Journal of Organometallic Chemistry 574 (2) : 276-278. ScholarBank@NUS Repository.
dc.identifier.issn0022328X
dc.identifier.urihttp://scholarbank.nus.edu.sg/handle/10635/93160
dc.description.abstractThe reaction of tBuNC with the osmium-antimony cluster Os3(μ-H)(CO)10(μ-SbPh2) (1) proceeded via Os-Os bond cleavage to give HOs3(CO)10(μ-SbPh2)(CNBut) (2) in which the tBuNC ligand was added onto one of the osmium atoms bridged by the antimony. Cluster 2 exists in isomeric forms, where the tBuNC ligand occupies either an axial (a-2) or an equatorial (e-2) position with respect to the Os3Sb plane. In solution, e-2 was found to occur as a mixture of isomers in which the isonitrile was presumably either cis to the unique osmium or to the antimony.
dc.sourceScopus
dc.subjectAntimony
dc.subjectClusters
dc.subjectIsomers
dc.subjectOsmium
dc.typeArticle
dc.contributor.departmentCHEMISTRY
dc.description.sourcetitleJournal of Organometallic Chemistry
dc.description.volume574
dc.description.issue2
dc.description.page276-278
dc.description.codenJORCA
dc.identifier.isiutNOT_IN_WOS
Appears in Collections:Staff Publications

Show simple item record
Files in This Item:
There are no files associated with this item.

Page view(s)

109
checked on Jan 20, 2022

Google ScholarTM

Check


Items in DSpace are protected by copyright, with all rights reserved, unless otherwise indicated.